Books & Software on Environmental Radioactivity and Pesticides

 

Environmental Research & Publications Inc.

Mailing Address:
P.O. BOX: 79023, Garth Postal Outlet,
Hamilton, Ontario, Canada, L9C 7N6

Business Address:
140 Golden Orchard Drive,
Hamilton, Ontario, Canada, L9C 6J6

Telephone: (905) 385-8111; Fax: (905) 385-8263; E-mail: porder@enviropu.ca

Environmental Research & Publications Inc is pleased to advertise the following books and software.

(1) DIFFUSION COEFFICIENT
AND MIXING DEPTH THROUGH
ENVIRONMENTAL RADIOACTIVITY
(MODELS AND APPLICATIONS)

ISBN 978-0-9696383-6-0 ; Year 2010; 331pp; 8x11; 45 Figures; 137 Tables; 365 Equations.
Price in Canada and USA US$ 245.00/ outside US$ 265.00. Taxes and postage by air mail are included.

Dr. B. S. Shukla, Environmental Consultant
***(RELATED TO SOFTWARE (2003) AND BOOK(2002) ON SEDIMENTATION RATE)***

This book deals with the abinitio derivation of advection diffusion equation (ADE) solutions by Fourier transform and applications of the solutions in the computation of biological diffusion coefficient (Dbi) and mixing depth (Lmi) in lake and sea sediment cores. A new model named as ADE-PEAK model is developed. The results of the ADE-PEAK model are compared with the ADE-STAT model due to Guinasso and Schink (1975) J. Geophys. Res. 80,21,3032-3043 and ADE-APPROXIMATE model due to Officer and Lynch (1983) Marine Geology,52,59-74. The theoretical reason and computation results prove that the ADE-STAT model is inapplicable. It is also proven that ADE-APPROXIMATE model underestimates Lmi and overestimates Dbi.

Click Here To Order

FEATURES:

It is demonstrated that ADE-PEAK model predicts the most accurate values of Dbi and Lmi. This book also solves the convergence problem in Fourier solutions as first encountered by Brenner (1962) Chem. Engng. Sci.17, 229-243. This book also solves an other type of the convergence problem in the application of Fourier solutions, known as Gibbs Phenomenon which occurs at the extremities of the finite length within which the solutions are applicable.

Table of Contents:

Chapter 1. OBJECTIVES AND SCOPE OF THE BOOK (1-8)
Chapter 2. EVALUATION OF ADE SOLUTIONS: PART-I (9-70)
Chapter 3. EVALUATION OF ADE SOLUTIONS: PART-II (71-96)
Chapter 4. EVALUATION OF ADE SOLUTIONS: PART-III (97-140)
Chapter 5. APPLICATIONS OF ADE:- PART-I BIOLOGICAL DIFFUSION COEFFICIENTS AND MIXING DEPTH IN SEA SEDIMENT CORES (141-201)
Chapter 6. APPLICATIONS OF ADE:- PART-II BIOLOGICAL DIFFUSION COEFFICIENTS, PEAK VELOCITY AND MIXING DEPTH IN SEDIMENT CORES (202-251)
APPENDIX- A: ADE SOLUTIONS BY FOURIER TRANSFORM (253-322)
REFERENCES (323-327)
AUTHOR INDEX, SUBJECT INDEX and SYMBOLS (328--331)



MORE ABOUT THE NEW BOOK:

In Appendix-A, advection diffusion equation (ADE) with decay constant λi is solved by Fourier transform under various initial and boundary conditions. The methodology is based on the standard text books on heat conduction in solids. Scientists, engineers and researchers with the background in physical chemistry, physics and mathematics can very easily understand the steps involved in the derivation of the ADE solutions. Chapters 2, 3 and 4 are devoted to in depth understanding of the profiles of the various ADE solutions by taking fixed values of diffusion coefficient,Di,  and advection velocity, Vi,  as 0.182 cm2yr-1 and 0.182 cm.yr-1, respectively. The exactly same values of Di and Vi were earlier used by Cleary and Adrian (1973) Soil Sci.Soc. Amer. Proc. 37, 197-199. The purpose of using the same Di and Vi values is to authenticate their results as well as the results reported in this book.  In chapter 2, λi = 0.0311386 yr-1 is used as required for the 210Pb profile, but in chapters 3 and 4,  λi = 0.0229747 yr-1 is used as required for 137Cs profile. In chapter 2, convergence problem in Fourier solution as related to the Péclet number, (P = Vi L/Di), is solved by defining a suitable length of a column, Lsp, which is named as Fourier-Shukla length.  By applying the principle of material balance, and by using the ADE solutions obtained by Laplace transform, it is proven that ADE solutions obtained by Fourier transform can be applied to any P provided Fourier-Shukla length is satisfied.  Lsp is a function of Di, Vi, and travel time t.  The convergence problem referred to as Gibbs Phenomenon is addressed with the help of Break Through Curve (BTC).The back calculation of Di and Vi by graphical method from the ADE pulse solution profile, proves that the calculated Di and Vi are time dependent and Di and Vi are not equal to 0.182 which is the input value to produce the profile.  In chapter 4, back calculation of Di and Vi by statistical moments (σ, μ, S), proves that statistical method under predicts Di and over predicts Vi and the values of Di and Vi are not constants but depend on travel time.  In chapter 5, results obtained by ADE-STAT, ADE-APPROXIMATE and ADE-PEAK models are compared and relative merits and demerits are explained.  ADE-PEAK model is based on the matching of peak position and peak concentration of the  field profile with the theoretical profile. ADE-PEAK model quantifies peak velocity and distinguishes between advection velocity, Vi, and peak velocity, Vp.  In chapter 6, ADE-PEAK model is applied to determine Dbi and Lmi based on 239+240Pu and 137Cs profiles.  In chapter 6, the model due to Goldberg and Koide (1962) Geochim. et Cosmochim. Acta 26,417-450, is also applied to 210Pb profile to determine Dbi and Lmi.

INTENDED BOOK USERS ARE: scientists, engineers and researchers in the university/research institute, affiliated with the department of geology, hydrology, limnology, civil engineering, environment, marine geology, oceanography, agriculture, nuclear waste, soil physics and mathematics.


(2) Sedimentation Rate
Through
Environmental
Radioactivity

(Models and Applications)
Dr. B. S. Shukla, Environmental Consultant

This book deals with the 210Pb dating of sediments. In this book, the CIC, CRS and ADE based models are formulated from their inception and the results of their application are compared. Variable sedimentation rate, diffusion coefficient and statistical methods to interpret the model results are some of the interesting features of this book. A new model is developed that yields both the diffusion coefficient and the sedimentation rate while considering the variation of porosity with depth. This new model is named as porosity variation (PV) model. Mathematical equations to model the 137Cs and 210Pb profiles under transient and steady-state conditions are presented in detail.

Click Here To Order

FEATURES:

By calculating the uncertainty in the dates of 13 sediment cores, it is found that both the CIC and CRS models predict unreliable dates when variations in the 210Pb activity with depth are highly non-monotonic. However, a combination of CIC, CRS and PV models in association with their uncertainty in the 210Pb dates, is helpful in predicting the most probable dates for the core slices. A computer program pertaining to PV model in GW-BASIC is given in the book to calculate both the sedimentation rate and the diffusion coefficient.

CONTENTS

Chapter 1. OBJECTIVES AND SCOPE OF THE BOOK
Chapter 2. CIC AND CRS MODELS OF 210Pb DATING
Chapter 3. FLUX MODELS OF 210Pb DATING AND 137Cs MOBILITY
Chapter 4. POROSITY AND MIXING EFFECTS ON 210Pb DATING
Chapter 5. DATA ANALYSES
Chapter 6. FUTURE RESEARCH AND MODELING NEEDS
APPENDICES
   A. PROPERTIES OF THE STEADY STATE SOLUTIONS.
   B. APPROXIMATIONS IN THE ADVECTION-DIFFUSION EQUATION (ADE) AS APPLIED TO 210Pb DATING OF SEDIMENTS.
   C. AUXILIARY EQUATIONS.
   D. LINEAR REGRESSION, DATA FILES, COMPUTER PROGRAM AND RESULTS.


ISBN 0-9696383-3-7,  2002,   198pp;  8x11;  7 Figures;  103 Tables;  224 Equations


Price in Canada & USA US$245.00/Outside US$265.00. Taxes and postage by air mail are included.

MORE ABOUT THE ABOVE BOOK:

Both the CIC and CRS models assume constant 210Pb flux at water-sediment interface, but CIC assumes constant sedimentation rate and CRS assumes variable sedimentation rate. Analogous to an ideal gas or an ideal solution, one can imagine an ideal sediment core. It is assumed that in an ideal sediment core there is no post-depositional changes in 210Pb profile due to mixing, diffusion, biological activity in the sediment, and water current turbulence at water-sediment interface. CRS model applies to an ideal core, but PV model is developed for a real core that has altered 210Pb profile due to mixing and diffusional processes. PV model assumes constant sedimentation rate like CIC model but it also includes difffusional term based on advection diffusion equation. (1) In this book relative uncertainty in CIC and CRS dates has been formulated and calculated for 13 cores. Based on the linear regression, the standard deviations in slope and intercept of PV model have been calculated for 13 cores. From standard deviations of the slope and the intercept, the PV model predicts the variability in diffusion coefficient and sedimentation rate. The preceding statistical analyses have led to the conclusion that in non-monotonic 210Pb profiles, both the CIC and the CRS dates are equally untrustworthy.(2) The uncertainty in the variable sedimentation rate as predicted by the CRS model, depends on the uncertainty in CRS dates, 210Pb flux value and concentration of 210Pb in the particular cores slice. In a highly non-monotonic 210Pb profile core, both the CRS dates and the variable sedimentation rates are not reliable. Sub-surface peaks and valleys in 210Pb profile correspond to low and high variable sedimentation rates, respectively, but their influence on 210Pb dating is not yet resolved. In this book detailed calculations based on the variability in the sedimentation rate by PV model and the relative uncertainty in the variable sedimentation rate have been combined to justify the existence of maximum sedimentation rates in 13 cores. (3) The various equations given under flux models in chapter 3 are expected to resolve the issue that peaks in 210Pb profile are due to biological activity or due to low sedimentation rates. Flux model equations are important as these equations are applicable under constant 210Pb flux condition which is the fundamental assumption behind the 210Pb dating of sediments.(4) Minimum variable sedimentation rate in a core slice has very drastic effect on CRS dates in a core.

INTENDED BOOK USERS ARE: scientists, engineers and researchers in the university/research institute, affiliated with the department of geology, hydrology, limnology, civil engineering, environment,marine geology, oceanography,agriculture, nuclear waste, soil physics and mathematics.

(3) Watershed, River and Lake Modeling through Environmental Radioactivity. ISBN 0-9696383-0-2, 1993, 227pp; 8x11; 168 figures; 38 Tables; 197 equations; By B. S. Shukla, Ph.D.; Price: In Canada & USA US$ 245.00/ Outside US$ 265.00. Taxes and postage by air mail are included. Payment is accepted in both US$ and equivalent Canadian dollars.

Click Here To Order

The above book describes the behaviour of pollutants in watershed, surface waters and bottom sediments of lakes and rivers. In the watershed, the removal of pollutant by runoff, soil erosion and infiltration has been discerned, formulated and exemplified. In the lake and river waters, the removal constants by sedimentation, outflow, food-chain, and biota have been discerned, formulated and exemplified. In the bottom sediments, the removal constants and residence times by diffusion and advection have been discerned, formulated and exemplified. Since this book describes the pollutant behaviour in three distinct but connected boxes, viz., the watershed, the river and lake waters, and the bottom sediments of the river and lake; the models are collectively named as 3-BOX model. The concept of branching decay constants has been invoked to define various removal constants and residence times.

This book applies the mathematics of diffusion - advection coupled with the first order rate constant and the general mass balance equations to the fallout and the natural radionuclides present in air, water and soil to predict their transport and accumulation in watershed soil, sediments, waters and biota. This is the first book that concurrently quantifies the removal of pollutants both by runoff and infiltration from watershed soil. The models developed in this book assume an effective surface soil depth in which pollutants are homogeneously distributed as introduced in the publication, Earth and Planetary Science Letters, 105(1991) 314-318, co-authored by Dr. B. S. Shukla. The importance of the book can be seen from the comments that appeared in the Soil Sci. Soc. Am. J. 58:991(1994), 58:1848(1994).

FEATURES

(1) The 3-BOX model has been successfully applied to: (a) alpine Rhône watershed of Switzerland (b) five largest rivers of Finland (c) the Great Miami River of USA and (d) the chain of the Great Lakes. (2) The radionuclides that have been employed in the modeling are: 7Be, 210Pb, 90Sr, 137Cs, and 239+240Pu.

CONTENTS

(i) Objectives and scope of the book

(ii) Basic concepts in aquatic modeling

(iii) Mathematics of 3-BOX model of river system

(iv) Application of 7Be and 210Pb in soil erosion

(v) 90Sr, 137Cs and 239+240Pu transport from watershed to river waters

(vi) Application of the 3-BOX model to the Great Lakes.

RELEVANCE OF THE ABOVE BOOK TO NUCLEAR WASTE DISPOSAL

Nuclear research centres throughout the world have been conducting many experimental and theoretical studies on the various aspects of the safe disposal of the high level nuclear waste since the inception of the peaceful uses of the nuclear energy. Nuclear waste forms can be either the spent fuel itself or a glass-ceramics containing the fission products and the a emitters. The waste form will finally have to be put to the rest in a deep geological formation.

The waste form in the geological formation may come in contact with the infiltrating water and release 239+240Pu, 137Cs and 90Sr by leaching processes. The leachate containing 239+240Pu, 137Cs and 90Sr will eventually migrate through aquifer and pollute the charging surface waters. The radioactive contaminants in the surface waters will end up in the food chain through drinking water and fish harvesting. The possibility of food chain contamination by these radionuclides has prompted the development of food chain models and the extensive study on the leaching of these radionuclides from the waste forms.

This book deals with the leaching and migration of 239+240Pu, 137Cs and 90Sr that have been deposited on the soil as a result of atmospheric nuclear weapon testing which peaked during 1963-1964. Significant quantities of weapon produced radionuclides have been falling on the soil and surface waters since 1954 till now. The rain water removes the atmospherically deposited 239+240Pu, 137Cs and 90Sr to surface waters by runoff and to ground waters by infiltration. This book describes the mathematical models and the results of the calculation pertaining to the removal of the atmospherically deposited 239+240Pu, 137Cs and 90Sr from seven watershed soils by rainwater via infiltration and runoff. The book also describes the partitioning of these radionuclides among biota, waters, sediments which in turn will be useful in evaluating the radiation doses to the general public through fish and water consumption. This is the first book that employs the naturally produced 210Pb and 7Be to estimate the soil erosion and other environmental parameters. The book is expected to be useful for the engineers, scientists, managers, and educators working in the field of nuclear waste management, health physics and soil physics, for years to come.

INTENDED BOOK USERS ARE: scientists, engineers and researchers in the university/ research institute affiliated with the departments of nuclear waste, hydrology, civil engineering, environment, agriculture, pesticides, the Great Lakes and limnology.

(4) Transport of Pesticides from Watershed by Volatilization, Infiltration and Runoff ( Models and applications). ISBN 0-9696383-2-9, 1996, 187pp; 8x11; 64 figures; 36 Tables; 306 equations; By B. S. Shukla, Ph.D.; Price: In Canada & USA US$ 245.00/ Outside US$ 265.00. Taxes and postage by air mail are included. Payment is accepted in both US$ and equivalent Canadian dollars.

Click Here To Order

The above book describes the use of the analytical solutions of the Advection diffusion equation (ADE) involving first order degradation constant (l ), in predicting the transport of pesticides from land to air, sub-surface waters, and surface waters by volatilization, infiltration and runoff, respectively. All the steps involved in the derivation of ADE for unsaturated soil are clearly stated. The method of Laplace transforms in solving the ADE is exemplified under different initial and boundary conditions. The analytical solutions of ADE are applied to explain the break through curves and slug movement of the degrading pollutants. New models have been developed and successfully applied to explain the volatilization of pesticides with low and high values of Henry's Law constant, KH. Equations to estimate l in presence of volatilization are also given. The name 5-Box model implies that pesticides applied on the soil can redistribute themselves among 5 boxes. Box-1, Box-2, Box-3, Box-4 and Box-5 correspond to watershed, surface waters, sediments, sub-surface waters and atmosphere, respectively. The equations and examples given in the book will be useful in initiating and planning new experiments on pollutant transport in the laboratory as well as in the field.

 

This is a multidisciplinary book. The book applies the mathematics of diffusion -advection coupled with the first order rate constant and the general mass balance equations to predict the transport of pesticides from watershed by volatilization, infiltration and runoff. The models developed in this book can be easily extended to the radioactive pollutants. This is the first book that concurrently quantifies the removal of pollutants by volatilization, infiltration and runoff from the watershed soil. The models developed in this book assume an effective surface soil depth in which pollutants are homogeneously distributed as introduced in the publication, Earth and Planetary Science Letters, 105(1991) 314-318, co-authored by Dr. B. S. Shukla and in the book "Watershed, River and Lake Modeling through Environmental Radioactivity, ISBN 0-9696383-0-2, 1993" by Dr. B.S.Shukla. Both the books are complementary to each other and give complete insight into the mathematical modeling of the transport processes that govern the movement of pollutants in natural and laboratory setups.

An addendum is also included with the book. The addendum to the book describes (i) the application of 5-Box screening model to 238 pesticides (ii) new and original equations that correlate % removal of a pesticide by runoff at the edge of field (RE), % removal of the pesticide by runoff at the mouth of the river (RM) in the basin and the ratio (g) of total farmland in the basin to total pesticide application area in the basin and (iii) the importance of the measurement of the frequency of appearance (F.A.) of pesticides in rivers. The new models developed in the addendum have been tested on the field data available in literature pertaining to the Grand, Saugeen and Thames rivers of Ontario, Canada. The predictions made by the models are in excellent agreement with the measured values.

FEATURES

Breakthrough curves, concentration profiles in soil columns, volatilization of low and high KH pesticides, runoff and slug movements. 61 Pesticides have been arranged in the ascending order of their Koc/t1/2 ratio and have been evaluated by various screening models.

CONTENTS:

(i) Objectives and Scope of the Book

(ii) Mathematics of 5-BOX Model

(iii) Research Models with Applications

(iv) Screening Models with Applications

(v) Future Research and Modeling Needs

(vi) Appendix-A: Derivation of advection diffusion equation (ADE) for unsaturated soil.

(vii) Appendix-B: Solutions of the ADE by Laplace Transforms.

(viii) Appendix-C: A few solutions of the ADE.

(ix) Appendix-D: Computation of the error function and other associated functions.

 

MORE ABOUT THE ABOVE BOOK

Pesticides have been playing the vital role in the augmentation of agri-food production. There is need to produce more agri-food to cope up with the growing world population. Pesticides will remain an essential part of the modern agriculture and, therefore, their transport from agricultural fields to surface waters, groundwater and air has to be monitored and fully understood. The research into the transport of pesticide by volatilization, infiltration and runoff is in evolutionary state. Both the theoretical and experimental works are not yet well organized as in the other fields of science. This book aims at providing the sound theoretical background for the subject which in turn is required to conduct future laboratory and field studies on the pesticide transport in the environment. The important results described in the book are as follows.

(1) The analytical solutions of ADE to predict BTC, slug movements and concentration profiles of pesticides in an unsaturated soil are fully explained. (2) The profiles of slug having different Di, Vi and l i are compared with the normal distribution curve and interesting results are obtained. (3) Volatilization of low Henry's constant, KH, pesticides is objectively explained based on the thin pesticide rich soil surface layer rather than on the presence of a stagnant thin air layer on the soil surface as assumed previously by other authors. In absence of advection, the cumulative volatilization of soil incorporated pesticide is shown to be proportional to Ö Di/Ö l i ratio, and, therefore, the volatilization behaviour should be assessed by Di, Vi and l i and not by KH which generally contributes very little to Di and Vi. (4) Equation is derived to make correction for volatilization loss while determining the degradation constant in laboratory. The two slopes observed in the pesticide decay curve in laboratory study are explained and formulated. It is shown that in the field scenario, pesticide is lost by infiltration, volatilization, runoff and degradation and, therefore, the t1/2 values determined from the field study are low and unreliable. (5) Many new equations are derived under research and screening models. (6) Pesticides are arranged according to the ascending order of their Koc (mlg-1)/t1/2(days) ratio and it is shown that pesticides with Koc/t1/2 ³ 20 are not threat to air, water and soil pollution. However, pesticides with Koc/t1/2 £ 20 should be judged on the basis of organic matter content in the soil and rain fall in the region.(7) Appendices A, B, C, and D give all about ADE, its analytical solutions and the computer program to compute erf(x), erfc(x) and eAerfc(x).

INTENDED BOOK USERS ARE: scientists, engineers, and researchers in the university/research institute, affiliated with the departments of pesticides, hydrology, civil engineering, environment, agriculture, nuclear waste, soil physics and mathematics.

(5) SOFTWARE (NEW VERSION, 2003): Pb-210 Dating of Sediments (Sedimentation Rate through Environmental Radioactivity: Part-I): ISBN 0-9696383-5-3, 2003; By B. S. Shukla, Ph.D.; In Canada & USA US$ 245.00/ Outside US$ 265.00. Taxes and postage by air mail are included. Payment is accepted in both US$ and equivalent Canadian dollars.

Click Here To Order

This new version of the software computes sediment dates and related parameters by five models, viz., Constant Initial Concentration(CIC), Constant Rate of Supply (CRS), Advection Diffusion Equation(ADE), Porosity Variation (PV), Porosity Variation Without Diffusion (PVWD) models. Based on ADE model, an addendum is enclosed to calculate diffusion coefficient of 210Pb in sediments. The PV model calculates both diffusion coefficient and sedimentation rate. The PVWD model includes the compaction effect of the CIC model and the total activity of the core as in the CRS model. The statistical component of the software calculates and compares the relative uncertainty in 210Pb dates for all the five models. The authenticity in the variable sedimentation rates solely depends on the relative uncertainty in the 210Pb dates of the model. It is important to reiterate that now variable sedimentation rates are predicted by all the above five models. The software package contains 55 page user guide booklet, 6 page addendum booklet and one CD-ROM. The CD-ROM included with this package has all the programs, data and output files in the folder Pbdates. Appendix-A in the guide booklet describes the background mathematics of CIC, CRS, ADE, PV and PVWD models. In Appendix-B of the guide booklet, 13 core results are given with interpretation. There are two sets of programs yielding the same results. The first set of two programs written in GW-BASIC language runs on DOS. The second set of programs in executable files runs in MS-Windows.

FEATURES

(1)Calculates (a) 210Pb dates, relative uncertainty in dates and variable sedimentation rates and all other parameters based on the 5 models (b) diffusion coefficient by ADE and PV models (2) Results are immediately displayed on the screen and stored on a diskette to get hard copy (3) Examples to prepare data file, to run the programs and to interpret the results. (4) Suitable for both research and routine uses.

Technical Requirements

Copy Pbdates folder from CD-ROM drive to C: drive. The application programs corecal2 and coredat2 can be run from CD-ROM drive or C: drive by Windows-95, 98, and XP on IBM compatible PC. The data files and the result files are to be written on C: drive. The steps involved in running of the corecal2 and coredat2 are fully explained in the guide booklet.

Technical Support: The package is sold with limited support by fax, telephone and E-mail.